VTS-ID/8225

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URL: http://vts.uni-ulm.de/doc.asp?id=8225
URN: urn:nbn:de:bsz:289-vts-82255

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Titel Bis(Terpyridine) monolayers on metal surfaces as 2D-model systems
Autor / Hrsg. Waldmann, Thomas
Dokumentart Dissertation
Institution Universität Ulm.  Fakultät für Naturwissenschaften
DDC-Sachgruppe Chemistry & allied sciences (ddc:540)
Schlagwörter
(): Schlagwortschema		 Adsorption (SWD)
Gold (SWD)
Interactions (custom)
Large counting statistics (custom)
Model system (custom)
Oberflächenchemie (SWD)
Organic adlayers (custom)
Organic adsorbates (custom)
Oxygen dissociation (custom)
Pyridine (LCSH)
Rastertunnelmikroskopie (SWD)
Rotating adsorbates (custom)
Self-assembled monolayer (custom)
Silver (LCSH)
STM (custom)
Surface rotations (custom)
Terpyridine (custom)
Variable temperature STM (custom)
Video scanning tunneling microscopy (custom)
Video-STM (custom)
2,4´-BTP (custom)
Sprache englisch
Jahr der Erstellung 2012
Signatur W: W-H 13.079
VTS-Veröffentlichung 07.11.2012
Statistik 129 Zugriffe seit 07.11.2012
Abstract Hydrogen bonded adlayers of the bis(terpyridine) derivative 2,4’-BTP on different single crystalline gold and silver surfaces were studied by variable temperature scanning tunneling microscopy (VT-STM) and Video-STM. The STM data is evaluated quantitatively, mainly by large counting statistics. The results are supported by DFT-D calculations and Monte-Carlo simulations. This work gives insight on the molecular scale on adsorbate-adsorbate interactions, adsorbate-surface interactions, interactions between adsorbates surface defects, surface reactions (reactivity of organic adlayers) and rotations of adsorbates.

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